Originally Posted By: SR5
Originally Posted By: Shannow
FYI, and I'm positive that it's not the issue for cams...(still trying to dig that stuff up)
When looking for marking pens and NDT chemicals, we need certification of low melting point metal and halide free marking pens and compounds.
http://www.corrosionclinic.com/types_of_corrosion/liquid metal embrittlement_LME.htm
Quote:
Liquid Metal Embrittlement (LME) refers to environmental cracking caused by contact with a liquid metal. It is also known or as Liquid Metal Cracking (LMC).
There is a specific combination of liquid metals and stressed metals or alloys that can lead to catastrophic intergranular cracking. For example, carbon steels and stainless steels are susceptible to liquid metal embrittlement by zinc and lithium; aluminum and aluminum alloys are susceptible to liquid metal embrittlement by mercury and zinc; copper and copper alloys are susceptible to liquid metal cracking by mercury and lithium. Cracking is frequently observed to be a single intergranular crack that propagates rapidly, at a rate of 25 cm/s.
Mercury-containing items are prohibited by all airlines as they pose a real risk to the structural integrity of the aircraft which is made of aluminum alloys.
Zinc from galvanized steel parts or zinc-rich paints is frequently found to be responsible for the cracking of welded steel components in various industries.
Mechanisms
What causes liquid metal cracking?
The mechanism of liquid metal cracking is clearly not electrochemical in nature. It is most probably an adsorption-induced cracking. The liquid metal atoms when adsorbed on a susceptible metal or alloy reduces the metal bond strength within the grain boundary regions of the susceptible metal. Under tensile stress, crack initiates and propagates rapidly along the grain boundaries.
Yeah I'm with you on the cams.
The certified safe marking pens makes sense if your turbines are make of high temperature steel (high Ni, Cr, Mo, etc alloys). I'm sure they have a lot of tensional forces when they start to spin. Add F / Cl / Br or low melting point metals and you are in big trouble.
I'm back at work next week, so I'll be able to chat with some metallurgists.
That reference you gave above said
"Zinc from galvanized steel parts or zinc-rich paints is frequently found to be responsible for the cracking of welded steel components in various industries."
I'll ask them about that too and how frequent it truly is.
So to continue this conversation, I spoke to some failure analysis engineers / metallurgists / chemists at work about this. They say the mode of failure of having liquid metal zinc causing intergranular fractures after welding is well know, and the correct procedure is covered by most welding standards and in trade training.
The cause is welding already galvanised (zinc plated) metal, melting the zinc with the heat of the electrode, then have this cause LMC. The solution is to remove all the zinc coating (by grinding) before welding, or ideally weld first and then plate second.
It's not an mechanism that would exist in an engine with a heavy ZDDP oil. It's at welding issue. No welding, then no zinc LMC problems.