Char Baby, what's that got to do with successfully "sucking out the tire fill" and "reinflating with nitrogen?"
You said "First of all." What's "second?"
Let's say you mean to say a tire will seal without air pressure having to be above ambient pressure (1 bar), which I doubt is the case. Do you seriously believe that it is possible to pump out the ambient air to any degree out of the tire with the tire still sealing against the rim?
Engineers, please!