Originally Posted By: EdwardC
Originally Posted By: JHZR2
Originally Posted By: EdwardC
The jump box I keep is a Lithium Iron Phosphate (4S) based pack, a safer lithium based chemistry, yet has very high discharge rates.
We have done a lot of testing on LFP. It will still outgas flammable electrolyte and burn. An LFP 26650 has an AC 1kHz impedance of around 8mOhm, and DC impedance is about double that so you can do the math. Still can provide a lot of juice...
Very interesting! LFP is supposedly much safer than other Lithium chemistries, at least according to the internet. Is that still accurate in your experience? How do they compare? I'm mostly concerned since I'm carrying around the LFP jump box in the car all over.
Sorry hijacking the jumper cable thread..
Happy to discuss. LFP does not have the same exothermic reaction under abusive and faiure conditions as typical metal oxide cathodes used in other Li-ion cells. That said, it doesnt mean that the cells are safe. The electrolyte in Li-ion cells can still vent at a few hundred psi, and in the presence of an ignition source (the electrolytes are conductive in the fas phase, so its assured) will burn in a typical organic fire, and this can easily produce propagation.
If one looks at cell impedance, it can be observed that the jumping amp rate is nearly shirt-circuit current level, and shorting Li-ion cells most often causes a flaming vent, regardless of chemistry. Further, Li-polymer cells will have worse impedance due to poorer conductivity and worse interfacial resistance, and thus will get hotter and have a more abusive condition to them.
Interestingly, looking on amazon, it appears that all these systems either have some kind of a timer-controlled MOSFET or have strict requirements to only leave the unit connected for 10 seconds or less.
These things are an interesting concept, and I have an external battery for my e-gadgets. But for operations at these discharge rates, and to sit in a trunk where the temperature can get dangerously close to the SEI-layer decomposition temperature, well, no thanks...