Old pennzoil bottle

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I came across two old (i dont know how old) pennzoil yellow bottles 5w30. On it said, "with Z-7." Does anyone know what this means and maybe when this was advertised?
 
This is a question for Johnny. I'm sure he'll see the thread and let us know what he knows
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Ya, I've got 2 cases of Pennsoil in cardboard cans. Both the 10W30 and 10W40 have the Z-7 on/in them.
 
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