Molybdenum

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Originally Posted By: SonofJoe
Let's see if this helps...

Some US PCMOs contain overbased Sodium Sulphonate. It's basically a cheap detergent. I might be wrong but I doubt if it does much other than mop up acid. I don't know but I suspect it was used simply to create a point of marketing differentiation.

Moly exists in many forms. Most people know about Molybdenum Disulphide which is a solid lubricant that functions a lot like graphite. However most Moly's in engine oil are in oil soluble form such as Molybdenum Dialkyl Dithio Carbamate (MoDDC).

Oil soluble Moly's are a bit like ZDDP in that they are true multi-functional additives. They're good for wear, good for oxidation control & good for engine deposits. They are also one of the few friction modifiers that actually delivers provided you add enough of it (around 1000ppm Mo in oil or 1%-ish MoDDC).

However Moly's are not without their problems. The biggest is cost. I've been away from things to know for sure but I'd guess that Moly is about ten times the cost of ZDDP on a metal in oil basis! This is hugely significant when you realise that whilst additive might only make up say 10-15% of an oil by mass, they roughly contribute about 40-50% of the overall cost of the oil.

In most global engine oil markets, Moly is used at relatively low treat rates either as a supplementary AO or AW additive. The only place you will find Moly used to its full potential is Japan. However you do need to understand that Japanese prices for engine oils are eye-wateringly high and are way beyond what other markets would tolerate.

PS, I tried to pour Moly on one of Santa's reindeers once. Sadly it died..


Excellent information! So to be clear it looks as if the moly content in oils is really not enough to proved the benefits this additive is supposed to provide? Is that what you're saying?

And back to the sodium, you're saying it's really just a cheap detergent, but I read in here that it is a metal. And if it's just a detergent, then what is the additive that provides engine/metal wear and protection in a product like Valvoline? Calcium? Because there's very little boron in it as well (and I thought boron was another anti wear additive).
 
Originally Posted By: doublebase
This same person also explained to me that my Toyota engine needed this oil and that Toyota engineers specifically and scientifically determined that the molybdenum content was necessary to ensure the quality of life that my bearing material needed (and I guess all of the 100 different engines Toyota manufactures are all the same and need it just as much).


This person is wrong. As long as the oil you use for your toyota meets the specs in the manual, you are good to go. You don't need the 'super special' TGMO. Whether you sleep better at night using it, that's a different matter.

Who was this anyway?
 
Originally Posted By: Leo99
My doctor says sodium contributes to high blood pressure.

Miley Cyrus says moly will make you happy.

What more do you need to know?


You know how that girl's tongue looks...it's definitely coated with something...perhaps moly, but I'm betting it's Slick 50. The good stuff of old.

I've never had a conversation in my life that didn't in some way shape or form involve some sort of Miley Cyrus angle. It's like the 50 shades of Kevin Bacon board game...it all comes back MC.
 
Originally Posted By: daman
I just had some on my toast this morning!! it slid right down with no wear on my esophagus !!


Esophagus...
 
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Originally Posted By: NYSteve
Originally Posted By: doublebase
This same person also explained to me that my Toyota engine needed this oil and that Toyota engineers specifically and scientifically determined that the molybdenum content was necessary to ensure the quality of life that my bearing material needed (and I guess all of the 100 different engines Toyota manufactures are all the same and need it just as much).


This person is wrong. As long as the oil you use for your toyota meets the specs in the manual, you are good to go. You don't need the 'super special' TGMO. Whether you sleep better at night using it, that's a different matter.

Who was this anyway?


Who was it? I don't know it's the Internet...let's assume it's Bill Gates nephew.

But it was the typical...Toyota engineers know more than you. They specifically formulate this oil through Mobil 1 to meet the demands of the stress that is placed on Toyota bearings. It provides a protective film that is second to none when used in Toyota applications.

And I have used it before, it seemed "good". I mean I couldn't go ahead and ask my engine...was that good for you? How do you feel? Aren't you glad daddy gave you that TGMO? I try that stuff on my dog after we drop her off at the boarding place when we leave the country...did they treat you good? Did you have fun? We paid an extra $50 dollars for them to take you swimming in their puppy pool, how did you like it? They said you played out in a field with lots of other dogs and you were so happy, how was that? Meanwhile they probably stuffed her in a box for a week and threw food at her right before we picked her up. She goes in there weighing 55 pounds and she comes out weighing 45. One year I had to carry her out of there because she was so weak. Yet she gets there and they charge me by her starting weight - I get no discount when they return her looking like a sack of bones.

As for the TGMO, I did seem to "like it", but it was a little too expensive when I can just buy a five quart jug of Mobil 1 for $22 at Walmart. True story --- I actually did ask for the TGMO for Christmas once. The case was wrapped under the tree. I was like a little kid opening it, but like most toys it lost its luster....especially when I drained it 6,000 miles latter into a pan.
 
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Originally Posted By: doublebase
Excellent information! So to be clear it looks as if the moly content in oils is really not enough to proved the benefits this additive is supposed to provide? Is that what you're saying?

And back to the sodium, you're saying it's really just a cheap detergent, but I read in here that it is a metal. And if it's just a detergent, then what is the additive that provides engine/metal wear and protection in a product like Valvoline? Calcium? Because there's very little boron in it as well (and I thought boron was another anti wear additive).


You should get a job with an oil company as a formulator. Really.
 
it might also be of benefit to add that in addition to its use in engine oils Mo is finding use in a range of other automotive products...

Off the top of my head i know its used in a range of different brake system lube products ranging from caliper and pin (along with silicon and graphite) to bearing lubes, and anti-friction dry lubes, engine building lube, pistons, etc....

it seems this element when used by itself and combined with other products (mainly silicon) provides a long lasting dry lubricant that is heat tolerant and friction reducing.

my cousin works at Honda and he says that they pretty much use Molykote on all brake jobs to ensure noise reduction and no returns for noise complaints
 
Last edited:
Originally Posted By: doublebase
Originally Posted By: SonofJoe
Let's see if this helps...

Some US PCMOs contain overbased Sodium Sulphonate. It's basically a cheap detergent. I might be wrong but I doubt if it does much other than mop up acid. I don't know but I suspect it was used simply to create a point of marketing differentiation.

Moly exists in many forms. Most people know about Molybdenum Disulphide which is a solid lubricant that functions a lot like graphite. However most Moly's in engine oil are in oil soluble form such as Molybdenum Dialkyl Dithio Carbamate (MoDDC).

Oil soluble Moly's are a bit like ZDDP in that they are true multi-functional additives. They're good for wear, good for oxidation control & good for engine deposits. They are also one of the few friction modifiers that actually delivers provided you add enough of it (around 1000ppm Mo in oil or 1%-ish MoDDC).

However Moly's are not without their problems. The biggest is cost. I've been away from things to know for sure but I'd guess that Moly is about ten times the cost of ZDDP on a metal in oil basis! This is hugely significant when you realise that whilst additive might only make up say 10-15% of an oil by mass, they roughly contribute about 40-50% of the overall cost of the oil.

In most global engine oil markets, Moly is used at relatively low treat rates either as a supplementary AO or AW additive. The only place you will find Moly used to its full potential is Japan. However you do need to understand that Japanese prices for engine oils are eye-wateringly high and are way beyond what other markets would tolerate.

PS, I tried to pour Moly on one of Santa's reindeers once. Sadly it died..


Excellent information! So to be clear it looks as if the moly content in oils is really not enough to proved the benefits this additive is supposed to provide? Is that what you're saying?

And back to the sodium, you're saying it's really just a cheap detergent, but I read in here that it is a metal. And if it's just a detergent, then what is the additive that provides engine/metal wear and protection in a product like Valvoline? Calcium? Because there's very little boron in it as well (and I thought boron was another anti wear additive).


Joe is right, but please don't read too much into his 1000ppm comments and then start breaking down engine oils based on VOA's only. There is a lot more going on in the packages than you can read using PPM counts of various elementals from a VOA. You aren't going to be able to break down an oil formulation based solely on what a basic VOA tells you.
 
Originally Posted By: Solarent
Originally Posted By: doublebase
Originally Posted By: SonofJoe
Let's see if this helps...

Some US PCMOs contain overbased Sodium Sulphonate. It's basically a cheap detergent. I might be wrong but I doubt if it does much other than mop up acid. I don't know but I suspect it was used simply to create a point of marketing differentiation.

Moly exists in many forms. Most people know about Molybdenum Disulphide which is a solid lubricant that functions a lot like graphite. However most Moly's in engine oil are in oil soluble form such as Molybdenum Dialkyl Dithio Carbamate (MoDDC).

Oil soluble Moly's are a bit like ZDDP in that they are true multi-functional additives. They're good for wear, good for oxidation control & good for engine deposits. They are also one of the few friction modifiers that actually delivers provided you add enough of it (around 1000ppm Mo in oil or 1%-ish MoDDC).

However Moly's are not without their problems. The biggest is cost. I've been away from things to know for sure but I'd guess that Moly is about ten times the cost of ZDDP on a metal in oil basis! This is hugely significant when you realise that whilst additive might only make up say 10-15% of an oil by mass, they roughly contribute about 40-50% of the overall cost of the oil.

In most global engine oil markets, Moly is used at relatively low treat rates either as a supplementary AO or AW additive. The only place you will find Moly used to its full potential is Japan. However you do need to understand that Japanese prices for engine oils are eye-wateringly high and are way beyond what other markets would tolerate.

PS, I tried to pour Moly on one of Santa's reindeers once. Sadly it died..


Excellent information! So to be clear it looks as if the moly content in oils is really not enough to proved the benefits this additive is supposed to provide? Is that what you're saying?

And back to the sodium, you're saying it's really just a cheap detergent, but I read in here that it is a metal. And if it's just a detergent, then what is the additive that provides engine/metal wear and protection in a product like Valvoline? Calcium? Because there's very little boron in it as well (and I thought boron was another anti wear additive).


Joe is right, but please don't read too much into his 1000ppm comments and then start breaking down engine oils based on VOA's only. There is a lot more going on in the packages than you can read using PPM counts of various elementals from a VOA. You aren't going to be able to break down an oil formulation based solely on what a basic VOA tells you.


I kind if figured that was the case, otherwise they wouldn't put it in there,my it he provided some good information. I do tend to get caught up in these formulas a little too much, when in actuality just buying a high quality product, changing it regularly and not beating on your car, is what's most important. But I still enjoy the topic regardless.
 
Is moly the greatest thing since sliced bread? Maybe, then again, maybe not - I've read enough articles to raise a Spockian eyebrow. The question for me is it necessary in my application. I run a 10w30 oil where HTHS, shear stability and volatility are my primary concern. Chasing the ultimate FM elixir is not.
 
Mobil 1? TGMO? WHY are you using those when there's a company called LIQUI MOLY
Check the UOA's, you might just find your fix there.
 
Aw man I was pronouncing it moly-bend-um in my head. Forget about the family catching gastro the other day, this has ruined xmas.
 
Originally Posted By: THafeez
Mobil 1? TGMO? WHY are you using those when there's a company called LIQUI MOLY
Check the UOA's, you might just find your fix there.


I have definitely seen and heard of Liquid Moly, but I don't recall the reviews and UOA's being anything unusually good (or at least better than others). I'll definitely check it out again and do some research. I kind of just buy Mobil 1 because it's readily available and it almost always seems to be on sale. The rebate program they ran last year was unbelievable, I was able to get myself 30 quarts and when it was all said and done I ended up paying $1.90 a quart. I can't even buy conventional oil for that. I have used TGMO before, it seems good...my engine used less oil than usual (not that I use much to begin with), but it was pricey for a guy who dumps his oil around the 6,000 miles mark...I went 8,000 miles on an extended performance oil once, but I didn't feel comfortable doing it (I have a timing chain engine with direct injection).
 
Originally Posted By: KL31
Aw man I was pronouncing it moly-bend-um in my head. Forget about the family catching gastro the other day, this has ruined xmas.


Yeah gastro always ruins Christmas (and Super Bowls). Never fails.
 
i changed my 2015 Suburban oil this past week with 8.5qts of moly-licious TGMO and knew right away something special was happening. "MOLYBURBDENUM" plates have been ordered.
 
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