Yes, I think that works out. If you pull numbers off the chart in posting #1, the green area near the beginning of the evening represents about 5 GW for about 4 hours, or 20 GWh which is 0.2 TWh out of a demand of 20 TWh for the day, or about 1% of the total.
I think you mean GWh, lol. 20TWh is roughly what they use in a month (245TWh/year). 20GWh is 0.02TWh.
Looking at the ElectricityMaps data, what's more interesting is what is charging the batteries.
2PM, battery is charging (one might assume solar, but they are running 5.18GW of gas so that's not clear), by 3PM, battery is no longer charging. 4PM battery is discharging at 3.3GW, 5PM, 4.91GW, 6PM, 4.06GW, 7PM, 3.16GW, 8PM, 2.59GW, 9PM, 1.72GW, 10PM, gone.
That puts us at 19.74GWh discharge, which is pretty close to your 20GWh.
11PM, battery is charging (and they are running 8.69GW of gas and there's clearly no sun), and this continues on (currently most recent timeslot is 2AM in Cali, battery is still charging with gas, since gas is on the margin).
So, what emissions reduction is a battery being charged with gas providing?
Even on a rather mild (low demand) fall day, 41% of their electricity came from gas, 192GWh. So they'd need 10x the battery capacity they have currently (and enough solar to charge it, solar generated 106GWh, total demand was 468GWh, wind provided a whopping 29.2GWh) to displace gas.
Assuming a super low price of even $400,000/MWh (it's more like $600,000 currently), that's $76.8 billion in batteries. They could basically build Vogtle twice for that money.