2012 Genesis 3.8L V-6 w/HIGH silver

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Originally Posted By: Phishin
Silver has a very high "shadow" effect in an ICP. .... So, if a sample had high silver, and then Blackstone ran your sample next and your sample had no silver in it, it might appear to have silver in it anyways. Silver and Lead are both "very sticky" in an ICP.

It's a possible explanation.


+1
 
Originally Posted By: Phishin
Here is a possibility:

Ask Blackstone to re-run your sample. Sometimes they will do it for free.

The reason I say this is, Silver has a very high "shadow" effect in an ICP. I run an ICP for a living. I'm a chemist.

So, if a sample had high silver, and then Blackstone ran your sample next and your sample had no silver in it, it might appear to have silver in it anyways. Silver and Lead are both "very sticky" in an ICP.

It's a possible explanation.


Thanks, Phishin. This is good stuff. I've learned something today! I was finding it a little difficult to believe that Hyundai would build engines with Silver bearings. Silver used to be a premium bearing material used in WWII aircraft engines. The only engines I know of that could be using Silver bearings nowadays are EMD locomotive 2-stroke diesels.
 
Originally Posted By: A_Harman
Originally Posted By: Phishin
Here is a possibility:

Ask Blackstone to re-run your sample. Sometimes they will do it for free.

The reason I say this is, Silver has a very high "shadow" effect in an ICP. I run an ICP for a living. I'm a chemist.

So, if a sample had high silver, and then Blackstone ran your sample next and your sample had no silver in it, it might appear to have silver in it anyways. Silver and Lead are both "very sticky" in an ICP.

It's a possible explanation.


Thanks, Phishin. This is good stuff. I've learned something today! I was finding it a little difficult to believe that Hyundai would build engines with Silver bearings. Silver used to be a premium bearing material used in WWII aircraft engines. The only engines I know of that could be using Silver bearings nowadays are EMD locomotive 2-stroke diesels.


Is there any way to verify if there is indeed silver in the bearings? I've also read it can be present in piston cylinder sleeves, valves, and valve guides.
 
Originally Posted By: Philth

Does Pennzoil Platinum, or other like synthetic, have ZDDP in it like the VWB does?

More so, if I drop my OCIs down to 3,750 (severe service intervals per owner's manual), is there ANY advantage to using synthetic at all in this application?


Between 3.5K and 4K OCI which is strongly recommended for DI engines subjected to severe service (mostly city driving, frequent short trips, idled often), you will likely not benefit to any appreciable degree by using synthetic oil. Therefore probably not very cost effective, especially if you pay more than $5 per qt for synthetic.

I personally rate certain motor oils for DI application, in this order, beginning from probably ideal down to possibly less optimal:

1. VWB, MS5K (low to mid SAPS)
2. QSAD Q State conventional, Motorcraft Syn Blend (mid SAPS)
3. QSUD Q State synthetic, PP, any WPP produced synthetic such as Peak synth and various store brand synth (on the low end of high SAPS)

M1 EP (the current SN GF-5 formulation) is a high SAPS oil, on the mid range of high SAPS.

It seems the original PP (A1/B1 and A5/B5) 5W30 was so good, it almost made you forget about the 10W30 grade. Never seen a poor UOA of that old PP 5W30. But the later version of the old PP 5W30, the one with Dexos1 label on the bottle, is only rated at ACEA A1/B1, Mainline Lubricant spec. ACEA A5/B5 is Upper Mainline Lubricant spec. But this could be marketing [censored] also, because M1 regular and M1 EP both are rated at both A1/B1 and A5/B5, and the 5W30 grade especially of M1 regular carries monthly complaints of it in BITOG, in both naturally aspirated FI and GDI FI applications. But if one takes the ACEA (I think it's Euro derived) specs seriously, QSUD 5W30 (the one with Dexos1 label on the bottle), although it's basically identical with PP 5W30 additive wise and both are acknowledged to be Group III synthetics, nevertheless QSUD 5W30 Dexos1 carries the weightier ACEA A5-02 spec which is predecessor to the A3/B3 spec that is intended for Autobahn operation. Again, it could be marketing [censored] concerning QSUD 5W30, because that's a Resource Conserving oil for CAFE purposes and for new vehicles, and for sure QSUD 5W30 has HTHS viscosity below 3.5 which is the minimum requirement for meeting ACEA A3/B3. Inconsistencies. Also, the new PP PurePlus (with GTL base oil) 5W30 is once again rated to meet/exceed both A1/B1 and A5/B5, whereas the new PP PurePlus 10W30 only meets/exceeds the easier specs SN and Resource Conserving GF-5. On the other hand, the Noack number of PP PurePlus 10W30 is incredibly much lower than the Noack number of PP PurePlus 5W30. 10W30 is going to have lower Noack than the 5W30 counterpart, but in this PP with PurePlus case, much much lower, as published by Pennzoil, and yet, Pennzoil says nothing of PP PurePlus 10W30 meeting any advanced ACEA spec. Inconsistencies.

In short, either 5W30 or 10W30 of the QSUD and PP synthetics is going to be a decent performer in your sump, but IMO not near optimal for a GDI engine.

Yes, PP and others also contain their own ZDDP. I learned through BITOG that the most useful byproduct of ZDDP undergoing chemical reactions is the phosphorus antiwear layer on metal surfaces subject to very high pressure, especially on iron.

Here I read of some Euro fully synthetic oil that does not contain the ZDDP family of compounds, but in general, motor oils almost always contain ZDDP at varying concentrations.

I mentioned Lubrizol, because over there ZDDP was discovered, I think either in the 1940s or the 50s, and IMO they know more about automotive lubrication than any other single corporate entity, well, not by much. When I use an Ashland product (Valvoline), the number one reason personally is because their oil additives are supplied by Lubrizol.

Infineum and Afton are two other major additive manufacturers that I am aware of, thanks to BITOG education. Both are also very high quality.

Both XOM and SOPUS oils carry Infineum's additives, generally speaking.
 
ed i was looking at this and a couple of other articles on needle and roller bearings.
The only place i can think of that they might be used in this non turbo engine is in the VVT system.

https://www.silverinstitute.org/site/silver-in-industry/bearings/

Originally Posted By: philth
I've also read it can be present in piston cylinder sleeves, valves, and valve guides.

There are some blocks with high nickel content like GM's Bowtie.
Looking back to old aircraft and some diesel engines you find silver in bearings and some blocks but they almost assuredly wont be in a modern automotive engine.
You may find they used nickel in the sleeve iron but probably not silver.

In valves and valve guides it wouldn't be common or necessary in modern materials.
I have the feeling you may be chasing down a ghost looking for it in engine parts.

After thinking about it the one area that i think the silver may be coming if it really isn't a mistake is from is some sort of sensor or switch/solenoid inside the engine.
Possibly an oil level sensor or VVT actuator or ??. Silver is used extensively in these types of components for contacts.
 
Originally Posted By: edhackett
Turbo bearing is a possibility. Silver is used sometimes used in plain bearings in turbos.

Silver may show up in cylinder liners and also in some oil coolers where it used as a solder.
 
Originally Posted By: edhackett
Turbo bearing is a possibility. Silver is used sometimes used in plain bearings in turbos.

Ed


My motor doesn't have a turbo.
 
Originally Posted By: Philth
Originally Posted By: edhackett
Turbo bearing is a possibility. Silver is used sometimes used in plain bearings in turbos.

Ed


My motor doesn't have a turbo.

Well, that eliminates that then.
smile.gif


I saw the current Genesis has one. Is it an option, or now standard?

Ed
 
Originally Posted By: edhackett
Originally Posted By: Philth
Originally Posted By: edhackett
Turbo bearing is a possibility. Silver is used sometimes used in plain bearings in turbos.

Ed


My motor doesn't have a turbo.

Well, that eliminates that then.
smile.gif


I saw the current Genesis has one. Is it an option, or now standard?

Ed


It's only available on the 4-cylinder Genesis Coupe.
 
I see where I got crossed up on the standard engine offerings between the coupe and sedan.

I doubt the silver is coming from wear. The proportions of the other wear metals are way too low to have the silver come from a wearing part. Silver does not play well with automotive oils. Special oils are required for large percentage Ag bearings. If it is used in standard automotive applications, it is used in small amounts in an alloy, usually copper, for bearings. Silver bearing solder, as mentioned by others is a good bet. I wouldn't worry, but do have your next sample analyzed to monitor and do some more research to find out possible non wear related sources in your particular engine.

Ed
 
Alright thanks, Ed.


Switching to PP just out of curiosity. I won't be able to have a UOA done until I return back from the deployment I'm about to leave on (~6 months).

Until then, I'll just tell the wife to take the car to the dealer for conventional oil change every 3,750. :-(
 
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Originally Posted By: tswm
Sir, with the spring season coming up, I am reasonably confident that your motor will be better served by running either VWB or MS5K 10W30 for 5K miles.


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