If it is due for a spark plug change soon, then I'd do a leak down test while changing them.
Otherwise, I'd wait and not do a UOA just yet, since it isn't driven long each time. Instead check this most recent oil change, daily after driving, then in a couple days, then 4 days, 8 days, and so on, extending the amount of time till the next check, except if it is taken on a longer trip that warms up the engine, then check right after that too. I mean educate her about the importance of checking it herself on this extending interval and then it is up to her to do it, or not... maybe a little reminder every now and then if she is forgetful.
If the vehicle isn't in terrible condition, then it could easily be worth DIY replacing the head gasket, but go ahead and replace the PCV valve now if it hasn't been done in a long time which it probably hasn't.
Telling her to walk for her health, it may not be as unreasonable in Seattle as it is in some areas where you don't really want the elderly walking in extreme heat or freezing weather that poses an ice-slippage risk. It is easy for younger people to assume that everyone is in perfect health as they get older but eventually that is no longer true and walking more doesn't necessarily fix that. YMMV. If she wants to drive then she ought to be able to if it is reasonably sustainable to keep a vehicle running.