I'm still here, just avoiding some sensitive topics.
Esters are produced by chemically reacting alcohols and acids. With diesters, the acids are white solid powders and the alcohols are oily liquids (not the drinking kind!). With Polyol esters (POEs), the acids are light smelly liquids and the alcohols are white solid powders or flakes. The acids and alcohols are mixed together in a reactor and heated to temperatures from 350 to 500F under agitation and vacuum, where they react together to form larger molecules called esters. After additional purification steps, the final ester product is a clear, water white to pale yellow, oily and essentially odorless liquid.
Compared to other common synthetics such as PAOs and Group IIIs, esters have superior high temperature stability, lower volatility, better film strength and lubricity, and better cleaning capability. They also help to dissolve more additives and keep seals pliable.
Esters are not very common in motor oils anymore because of their high price, but they are used at additive dosages to enhance PAOs, mainly by balancing seal swell, solubilizing additives, and providing lubricity. Their main performance advantage - high temperature stability - is not generally needed in car engines, so PAOs or PAO/ester blends often provide better value. In hot applications, however, such as jet engines and certain industrial uses, esters are used extensively as the sole base oil.
Tom