I know my dad used to use MMO in his 79 Chevy van that had over 360k on it when he got rid of it. He added MMO to gas and oil, and changed the oil once a year whether it needed it or not. Hint: it definitely needed it! LOL
I don't have any kind of proof, since that was long before I was old enough to know or care about oils and engines, but I do think that back then, with "dirty" gas and "poor" engine oils, there may have been some benefit to using MMO to help dissolve some of the buildup from each of those fluids. Today, I don't know if the benefit of the product exceeds the cost of it. I think "older" engines fall into this same category- because the oils are better and the fuel is cleaner, I don't know if you still need MMO.
Same thing with TC-W3. Sure, I have used both products, but I can't say I've seen any benefits. Even when tracking mileage, checking UOAs, etc... nothing outside of statistical noise showed up. Can you use it because it makes you feel nostalgic, and like you're helping your machine? Certainly. Is there any anything other than anecdotal evidence to validate your use of these products? Most likely not.
Try one/either/both and see what your results are, and make a future decision based on that. That's about as honest an answer as I can give.