Originally Posted by RDY4WAR
Originally Posted by PimTac
Originally Posted by RDY4WAR
More information on the polar vs non-polar of PAO and how it applies to all base oils?
https://www.bobistheoilguy.com/
I've read that before and don't recall anything in there about PAO being non-polar. Great explanation of the base oils, but doesn't answer my question.
It's not nonpolar. However, it's not terribly polar. The example I remember from high school chemistry was that water is polar and that's basically why it's the universal solvent that dissolves many ionic compounds. A stream of water would be attracted to a positively charged rod, and would also be attracted to a negatively charged rod.
But I guess it's not quite that PAO is absolutely non-polar. It's all relative to other molecules.
Quote
https://www.machinerylubrication.com/Read/31106/polyalphaolefin-pao-lubricants
Polyalphaolefin Characteristics
Polyalphaolefin does not contain ring structures, double bonds, sulphur, nitrogen components or waxy hydrocarbons. The absence of these structures and materials results in a very non-polar base oil with a high viscosity index (of approximately 130), excellent low-temperature flow and pour-point characteristics, good oxidation stability and compatibility with mineral oils, paints and seals commonly found in lube oil systems. Because of their controlled structure, PAOs do not contain lighter, more volatile (small) hydrocarbons. This lowers their volatility, creates less hydrocarbon tailpipe emissions and raises the flash point.
PAOs are used extensively in automotive fluids as well as hydraulic, gear and bearing oils, working in extremely cold climates or hot applications. They are also employed as base fluids in some wide temperature range greases. One application in which they have not worked well is in high-temperature (high-pressure) reciprocating air compressors where valve deposits have been an issue.
However, nothing is perfect, and polyalphaolefin base oils do have a few negative characteristics. These include the tendency to shrink seals and trouble dissolving common oil additives. Therefore, they are commonly blended or combined with organic ester synthetic base oils to provide a blended base oil that does not have these negative characteristics. Polyalphaolefins also have poor fire resistance and biodegradability.