History of MMO
>Marvel Mystery Oil was formulated by GMC's Buick plant during the 1920's to keep the jets in Marvel Carburetors clean and working
That's essentially correct. In the 1920s, gasoline was unstable, and could oxidize to form varnish. But that has nothing to do with the fuels of the last 50 years, which are stable, and for the last 30 years include detergents to keep fuel injectors clean.
"Aviation Consumer" had MMO analyzed, and it is a single-weight oil with a viscosity rating of 4, peppermint odor, blue dye, and contains phosphorus (presumably triphenyl phosphate, which is what's in Alcor TCP and Lycoming LW-16702 additive). In oil, it acts as a solvent and dilutes the base viscosity. In fuel, it lowers the octane rating slightly.
MMO is often mentioned as a "cure" for valve sticking. John Schwaner says "Do not use MMO or other solvents to unstick a valve. Eventually the valve may unstick, but not before your camshaft lobes have been damaged. Solvent treatments dissolve the outer deposit layers in the guide boss and temporarily unstick the valve. The remaining deposits push the valve over to the opposite side of the guide and cause rapid, uneven guide wear." He goes on to describe the results.
http://www.sierra.net/skyranch/frame1.htm select "Stuck Valves"
and more!
Although there have been several replies to the question:
> What's TCP?
here's a trivia note: use of TCP tricresyl phosphate, was discontinued in 1990 due to health concerns. It was replaced with TPP triphenyl phosphate.
HC = CH HC - CH
/ \ // \\
R - C C - O - P - O - C C - R
\\ // | \ /
HC - CH O HC = CH
|
C
// \
HC CH TCP: R is CH3
| ||
HC CH TPP: R is H
\\ /
C
|
R
TPP has very similar properties, but there is some doubt about its effectiveness. Both are toxic and corrosive, and should be handled with gloves and good ventilation.
Shell 15W50 and Phillips 20W50 include TPP as an EP extreme pressure additive. Marvel Mystery Oil contains phosphorus, presumably as TPP. Lycoming sells TPP as LW-16702, and Alcor as "TCP".
Contrary to one previous posting, TCP affects neither the octane rating of gasoline, nor the viscosity index of oil.
TCP is an EP extreme pressure additive for oil: On the cylinder head walls, TCP reacts with clean steel surface to form a soft iron phosphate monolayer. The rings tear this soft monolayer off during each power stroke, thereby reducing wear to a single atomic layer of iron, instead of ripping several layers of unprotected steel. It has the same reaction on Lycoming camshafts, which are not otherwise lubricated during cold starts. Its use is recommended in Lycoming Service Bulletin 446C to deter camshaft
scuffing during start-up and initial cold running.
Aircraft engines are intentionally designed to burn oil, and steel cylinder head walls are designed to wear out, in about 8000 hours.
Unlike the EP additives used in automotive oils (zinc dithiophosphates), TPP is ashless and does not erode silver alloys used in certain Continental front-end and Lycoming supercharger bearings.
TCP can be used as a lead scavenger additive for fuel: TCP is more volatile than ethylene dibromide, so is better distributed to all the cylinders by the induction system of carbureted engines. (Lead is not an octane enhancer; it is the ethyl radicals formed by the thermal decomposition of tetraethyl lead that are the octane enhancers. These combine with radicals from fuel, thereby quenching spontaneous combustion, or detonation.) During combustion, TCP reacts with lead to form a soft lead phosphate, which can be blown out the exhaust, rather than forming a hard lead oxide deposit sticking to the spark plugs, valve guides, etc.
Sorry for all the trivia, but sometimes technicalities get a bit hazy in rec.av. Remember Netiquette #6, friends: "Look things up."
--
[ June 22, 2005, 01:43 PM: Message edited by: Gary Allan ]