aside from the danger in freezing your finger, you really dont want to breath in the refriderant your body cant expel it, it has to be absorbed into the body, as the fellow above mentioned, i might bet tempted to loosen a fitting and let it bleed off slowly.
i fix furnaces and air conditioners for a living, i wouldnt bleed off the r 134a myself, not just because i have the right tools, which helps of course, its one of the things i can do to help protect our earth, such as recycling oil as i am sure guys do on this site, not saying i am enviromently perfect at all, i have my ways i need to improve on in that regard,
if i can help any one with advice regarding air conditioning or home heating i would like the opportunity to give back to the form