Gremil, … a few points …
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Viscosity index always favors the Group IV.
Not always, one has to dig a little deeper here to ferret out more of the facts. It would be more correct to say VI generally favors GIV over GIII. There are 2 types of Group III base oils, hydrocracked and wax isomerates.
Hydrocracked Group III base oils (this represents most of the Group III production) typically have a VI in the 123 - 128 range although Chevrons UCBO 7R (7cSt) is 135 -- very close to PAO's which are typically in the mid to high 130's.
Group III+ (wax isomerates from XOM, Shell) typically have a VI 140+. The wax isomerates in this article
patentstorm… were 141 - 147. This is better than PAO's (which are usually under 140).
There are also GTL (gas-to-liquids) which fall into the Group III category, and they have specifications and properties almost identical to wax isomerate GIII+'s. Major production of GTL base oils was suppose to start around 2008, but have been pushed back as much as 6 years. One article I read hinted that some people actually consider these GIII GTL's a step up from PAO's.
Also, the lighter PAO base oils (4cST) see a significant drop in VI over the heavier PAO's -- and have a VI usually in the mid-low 120’s. The Chevron-Phillips
chevron 4cSt PAO is listed at 123, even lower than many 4 cSt Group III’s which come in around 123-128. The 4cSt GIII+’s (XOM, Shell) have a VI of 141-143 -- much higher than equivalent PAO's. This
might be a concern with 0W blends like 0w-30 -- which can use a significant about of 4 cST PAO.
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Shear stability favors the Group IV
Depends. The shear stability of GIII+ based oils are probably better than PAO's. But again the overall picture even comparing to GIII's isn't always so simple. Consider 2 Amsoil synthetics and their VI…
Amsoil XLF 5w-30 (GIII) 173
Amsoil ASL 5w-30 (PAO) 185
There is a 12 point spread in the VI of these 2 finished oil formulations. The PAO base oils probably have about a 12 point VI advantage over the GIII base oils -- lets say 138 vs 126. In that case both finished oil blends need to make up a 47 point VI spread. This means essentially that the PAO blend will likely be using as much VII's as the GIII blend (assuming VII's affect both base oils similarly) to make the VI spread. Since it's essentially the VII's that shear down (and not the base oil), these 2 oils should probably exhibit very similar sheer stability. Modern VII's are likely better than they were in the past, so this is less of a concern today.
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Fire point always favors the Group IV …….In the Group III motor oils the volatility will be higher than the Group IV.
The fire point of GIII base oils is essentially a match for that of PAO's. The volatility of GIII base oils is very close to that of PAO base oils. Even though the GIII base oils are close to the PAO's in volatility -- and a match for fire point. The advantage of blending with PAO’s over GIII (for NOACK) is that PAO’s flow better in the cold, so, one can blend with higher viscosity base oils and still meet the cold specifications (CCS/MRV) for that oil blend. This translates to perhaps as much as a couple % NOACK advantage based on using a thicker base oil -- and perhaps a little fire point advantage. GIII+’s (both wax isomerates and GTL's) have better cold flow properties than GIII so they would be very close to the PAO's and shouldn't give up much at all in the way of NOACK.
PAO's certainly have a couple of advantages over standard Group III's, but I don't think that difference so large as to be really … that … concerned with it. I can live with a few % higher NOACK considering the price of GIII motor oils -- they represent good value. If only PAO's were available for synthetic oils, we'd be paying more -- because the base oils are quite a bit more expensive. Does one want a GIII motor oil at $6, or a PAO base one at $8? When I think of the great price deals some people here have gotten brand name synthetics for (the stashers -- you know who are
) I don't think we'd be seeing these type of deals if they were PAO based motor oils.
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Make a note, while this isn't easy, many companies put their technical data in different places on their websites, others make them "available on demand" and you'll have to ask for the information. But being resourceful you will come to the same conclusion as I did:
My observation is that a few of the numbers on the data sheets (particularly for NOACK) don't really seem that accurate some of the time.