Originally Posted By: kschachn
Originally Posted By: Ducked
Dunno. Wikipedia doesn't give a date for the origination of the process, but I suppose more extensive searching might turn one up.
" Ferrous metals are commonly anodized electrolytically in nitric acid, or by treatment with red fuming nitric acid, to form hard black ferric oxide. This oxide remains conformal even when plated on wire and the wire is bent"
Right, and that black coating is a mixture of oxides, mainly iron (II) and iron (III). No one seriously involved in metal coatings would do that, it requires a secondary means of protection besides those oxides. And that is in no way what the previous poster was implying.
Just addressing your question.
A better answer might be "since 2007" according to these guys.
http://infohost.nmt.edu/~burleigh/JECS_2007.pdf
They mention an acidic process in their introduction, but only give detail for alkaline treatments, as background to their own process.
That assumes you want it to be (somewhat) usefully anodised, of course. I've never had any problem getting iron to anodise to rust.
I think the poster above was describing cathodic protection, so, IF any "ised" ("ized") applied in that case, it'd be "cathodised".