DOT 3 DOT 4 and DOT 5.1 are Glycol based brake fluids whereas DOT 5
are Silicone based... Glycol based fluids are designed to signal
moisture contamination... the fluid will start to turn golden, then
light brown, indicating that it has absorbed progressively more
moisture. Eventually, if left unchanged beyond the recommended service
interval, the fluid will become dark brown, indicating high amounts of
water absorption and thus badly contaminated fluid... user friendly
Glycol based fluids also reduce the effect of both corrosion and
compressibility because it is not only designed to accept significant
amounts of moisture, but even to neutralize it by dispersing this
moisture evenly throughout the system, thus preventing its
concentration in any one area...
Boiling point of Glycol based brake fluids
DOT 3 205 °C (401 °F)
DOT 4 230 °C (446 °F)
DOT 5.1 270 °C (518 °F)
If you wish to use the latest in Glycol base fluids then its DOT 5.1
Silicone Brake Fluids
DOT 5 Silicone based fluid will not turn color to signal moisture
content...
Boiling point of Silicone based brake fluids
DOT 5 260 °C (500 °Silicone Brake Fluids
In years past, all brake fluids were glycol. Then D.O.T. 5, a silicone
fluid having a higher temperature rating, emerged, initially to meet
the higher boiling point requirements of racing use. (Race car brake
systems include oil-cooler-like heat exchangers and ceramic pads.)
Silicone fluid was able to withstand the most heat of any brake fluid,
so it earned a reputation as a racing brake fluid. However, silicone
brake fluid has properties very different from glycol fluid, and has
its own pros and cons. On the advantage side, silicone fluid will not
harm paint or plastic, and does not aggressively attract additional
moisture as glycol fluid does. On the disadvantage side however,
silicone fluid aerates easily. Harley-Davison, one of the sole current
OEM users of silicone fluid, warns buyers to let the fluid sit at
least an hour before using it. The trip home in the saddlebag is
enough to aerate silicone brake fluid until it looks like a freshly
poured soft drink. Silicone fluid is also slightly more compressible
than glycol fluid, does not change color to tip the user to its
moisture content, and worst of all, neither accepts or disperses
moisture, making systems using it more corrosion prone, and requiring
much more frequent fluid changes. Silicone brake fluid also lacks
glycol fluid's naturally occurring lubricity, making it incompatible
with the mechanical valving in some antilock braking