what vehicle you working on?
i had the same problem on my 2006 sierra truck, has rear disc but the parking brake shoe is on the inside of the rotor. what happens is the parking brake shoe wears into the rotor but the shoe doesn't retract all the way because everything in there rusts and seizes so the parking brake shoe holds the rotor on. you'll know when you can wiggle the rotor and know it's not rusted to the wheel hub flange but doesn't pull off more than 1/8".
if it's rusted on the wheel hub, you need a heavy sledge and wack outward on the inside of the rotor and they usually dislodge off the hub easily. you can't use a 1 or 2 lb hammer, you need a full size sledge with a 18lb head or better, then one hand it against the inside of the rotor outward. the mass of the sledge will easily free the rotor off the hub if it's rusted to it. but getting the rotor off the parking brake shoe may be the biggest problem, worst case is you break the parking shoe and have to put new ones on. keep rotating the rotor and wacking on the inside of it and it'll come off. you can usually mail order the parking brake kit like the adjuster and stuff for cheap, the parking brake shoes are not that cheap. but unless you really bend or break the shoe in half, it's almost always useable. you'll be wasting your time with propane unless it's running off a 20lb bottle and is the gun you use to melt asphalt on your driveway. a handheld propane torch or any other won't produce enough mass heat, it'll be too localized. and if you had enough heat you'll definitely be cooking any grease or oil in a wheel bearing and melting seals.