There are inexpensive, readily available, anti-oxidant and anti-corrosion greases that do not have the ultra high resistivity of dielectric greases. Why not use them, if you like to coat the post and connector before making the connection? In making an electrical connection, why would anyone want to use a product, such as dielectric grease, that is specially formulated to block electrical current?
One such example of a non-dielectric, anti-oxidant grease is Ox-Gard, manufactured by Gardner Bender, and widely available in hardware stores, in the electrical aisle. One small tube should last the average car owner decades.